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If you're not sure if the other person's organization has open federation, contact them first by phone or email to ask.
Skype-to-Skype communication is a term we use to denote a direct connection between two Skype for Business clients for the purposes of voice, video, chat and/or desktop sharing.
Given the amount of data being transferred in an audio call (and even more in a video call), the amount of storage Skype would require to record everything would be .
So enormous that in my opinion, wholesale recording of all Skype traffic is quite impractical.
Changing your primary email address (Skype for Business login) can cause issues with Skype for Business' "presence" function and with reoccurring Skype for Business online meetings you have already scheduled.
Please see our Knowledge Base article for more information. KU has implemented "open federation," which means you can connect with other Skype for Business users at more than 800 institutions around the world that also have open federation.